Mr. Wakabayashi(M1)’s work on an air-stable hexa-NHC iron(II) complex has been published in Inorganic Chemistry

Mr. Wakabayashi(M1)’s work on an air-stable hexa-NHC iron(II) complex has been published in Inorganic Chemistry, entitled “Air-Stable Fe(II) Hexa-N-Heterocyclic Carbene Complex and Its Photoexcited State Dynamics.”

We synthesized a novel, air-stable Fe(II) hexa-NHC complex using triazole-based ligands, which stabilize the Fe(II) state due to their specific electronic donor properties and shift the MLCT absorption into the UV range. While the excited-state lifetimes remain in the picosecond range, the complex’s high stability under ambient conditions establishes a promising platform for developing future iron-based photosensitizers.

 

Air-Stable Fe(II) Hexa-N-Heterocyclic Carbene Complex and Its Photoexcited State Dynamics
Takuto WakabayashiTomohiro Ogawa*, Teruyuki Honda, Kaito Segawa, Toshiki MochimaruTatsuya YoshidaKiyoshi Miyata*, and Ken Onda*
Inorg. Chem. 2026, 65, 1, 767–775 (2025).

Laboratory of Spectrochemistry, Kyushu University
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